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Detailed Hydrocarbon Analysis and SIM DIS, Miscellaneous - Skinner List - Fire Debris, LUFT/LUST (UST) Methods - State Specific - GRH - DRH - TPH, Oil, Grease & TPH - EPA Methods 1664 - 413.2/418.1 and 8440, Wear Metals (Organometallics) and Lubricating Oils, Technical Service - Frequently Asked Questions, Sorry, there is currently no SDS available for catalog number ALR-CFC-010S-2X. When heated to decomposition it emits toxic vapors of F − and Cl −. Since Freon has a high vapor density, children could also receive high doses due to their short stature and the higher levels of Freon vapor that may be present near the ground when Freon is spilled. Like Freon-11, Freon-114 is a commonly used refrigerant that has been implicated in the destruction of the ozone layer. Shop a large selection of EPA Methods Standards products and learn more about 1,2-dichlorotetrafluoroethane (Freon 114), Restek. Boiling Point. Do not take internally. Freon, (trademark), any of several simple fluorinated aliphatic organic compounds that are used in commerce and industry. Note that the octet … The length of exposure was 15, 45 or 60 seconds. Overexposure may cause dizziness, nausea, muscle weakness, narcosis and respiratory failure.\nHighly Flammable (Flammable liquids, category 2)\nCauses damage to organs. Eye wash and safety equipment should be readily available. CAS No. 17034 Classification. 38°F. The most common representative is dichlorodifluoromethane. The store will not work correctly in the case when cookies are disabled. JavaScript seems to be disabled in your browser. Safty information about Freon 151 (CAS NO.1615-75-4) is: Low toxicity by inhalation. Freon 114 (76-14-2) is a colorless, nearly odorless nonflammable gas.It may be mildly toxic and irritating by inhalation and it can asphyxiate by the displacement of air.Following is the structure: Product Categories about Freon 114 (76-14-2) are Industrial/Fine Chemicals ; CFC ; Refrigerants ; Organics The column exhibits peak shape and resolution that is superior to the same application on Fluorcol packing. (P331)\nStore in a tightly closed container. Shipped as a liquefied compressed gas.] Freezing Point. Chlorofluorocarbons and hydrochlorofluorocarbons are fully or partly halogenated paraffin hydrocarbons that contain only carbon, hydrogen, chlorine, and fluorine, produced as volatile derivative of methane, ethane, and propane. The experimentally measured molar mass of this compound is 171 g/mol. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Chemical structure; Freon = 12: ... Freon = 114: Dichlrotetrafluoroethane: Freon = 22: Monochlorodifluoromethane: CASE REPORTS. For the best experience on our site, be sure to turn on Javascript in your browser. Assure adequate flushing by separating the eyelids with fingers. Call a physician or poison control center immediately. Molecular Weight. [Note: A liquid below 38°F. They are also commonly known by the DuPont brand name Freon. 1,2-dichlorotetrafluoroethane, CFC-114, Freon 114, Genetron 114, Forane 114 Freon is a registered trade name for E. I. DuPont. Peak blood concentrations of Freon 114 are reached immediately at the end of a short-term aerosol or vapor exposure (Dollery et al. (Acute toxicity, oral, category 3)\nHarmful if inhaled. 1,2-dichlorotetrafluoroethane, C2Cl2F4, is a refrigerant commonly known as Freon-114. 76-14-2 - 1,2-Dichloro-1,1,2,2-tetrafluoroethane (Freon #114) - AccuStandard. ChemIDplus - 76-14-2 - DDMOUSALMHHKOS-UHFFFAOYSA-N - Cryofluorane [INN] - Similar structures search, synonyms, formulas, resource links, and other chemical information. Molecular structure of freon 114, computer artwork. Answer: C 2 Cl 2 F 4 In addition to fluorine and carbon, Freons often contain hydrogen, chlorine, or bromine. (P338)\nSkin contact: Immediately wash skin with soap and plenty of water. Thus, Freons are types of chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and related compounds. Certified Reference Material. 1972). (Eye damage/irritation, category 2B)\nCalifornia Proposition 65 Warning: This product contains a component (or components) that may cause birth defects or other reproductive harm in a quantity greater than or equal to 0.1%. Freon #114. 1970; Morgan et al. (Acute toxicity, dermal, category 3)\nToxic if swallowed. 1,2-Dichlorotetrafluorethane. FREON 114 - chemical information, properties, structures, articles, patents and more chemical data. • Lucite®-acrylic resin (methacrylate polymers): dissolved by Freon 22 but generally suitable for use with Freon 12 and Freon 114 for short exposure; with long exposure it tends to crack, craze, and become cloudy; use with Freon 113 and Freon 11 may be questionable Catalog Number. (P404)\nDo not get in eyes, on skin or clothing. Always use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). It is a non-flammable gas with a sweetish, chloroform -like odor with the critical point occurring at 145.6 °C and 3.26 MPa. (P360)\nIngestion: Do NOT induce vomiting. R-114 is a colorless and odorless CFC refrigerant that was completely banned from production by 1996 under the Montreal Protocol for depleting the ozone. This treaty called for (1) limiting production of specified CFCs, including 11, 12, 113, 114, and 115, to 50% of 1986 levels by 1998, (2) freezing production of specified Halons 1211, 1301, and 2402 at 1986 levels starting in 1992, and (3) convening the signatories yearly to reevaluate and update the Protocol articles in light of recent developments. Since that time, studies on the synthesis of CFCs and their applications have progressed in many directions, such as aerosol, blowing agent for foam manufacture, fire extinguisher, cleaning solvent, … (P280). Freon 114 can be absorbed through the skin and gastrointestinal tract, but inhalation is the most common route of exposure, and exhalation the most important route of elimination. (P262)\nThis product should only by used by persons trained in the safe handling of hazardous chemicals. Ref: September 24, 2003 (Revised) - FREON [11, 12, 113]. Genetron is a registered trade name for Allied Signal Corporation. Air conditioners sprout from windows in a building in New York. S Sousa et. It is listed on the Intergovernmental Panel on Climate Change's list of ozone depleting chemicals, and is classified as a Montreal ProtocolClass I, group 1 ozone deple… alThe Journal of applied bacteriology, 63 (6), undefined (1987-12-1) An initial investigation was made of the bactericidal and sporicidal activity of the dry cleaning solvent Freon-113 (1,1,2 … Its primary use has been as a refrigerant. Freon ® 114 Compound Information and Applications for GC (Gas Chromatography) and LC (Liquid Chromatography) Analysis Find another compound: 1,2-Dichlorotetrafluoroethane Abstract: Ten subjects were exposed to the propellants freon 11, freon 12, freon 114, to two mixtures of freon 11 and 12 and to a mixture of freon 12 and 114. All Rights Reserved, 1,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 114 [UN1958] [Nonflammable gas], 1,2-Dichloro-1,1,2,2-tetrafluoroethane or Refrigerant gas R 114 [UN1958] [Nonflammable gas], 4-01-00-00137 (Beilstein Handbook Reference), Ethane, 1,2-dichloro-1,1,2,2-tetrafluoro-. A combination of sodium cyanide and hydrobromic acid administered ip to rats had an antagonistic effect. Calculate the molecular formula of Freon-114, which has 13.85% carbon, 41.89% chlorine, and 44.06% fluorine. A mixture containing 33 parts Freon 12 and 66 parts Freon 114 comprising 8% by weight of the polymer blend was injected into the melt by means of a metering pump. Freon-114B2, a narcotic, inhibited tissue respiration at the flavoprotein and cytochrome stage; the cyanide affected the oxidoreductase and, in part, the cytochrome/oxidase systems. In addition, the polarity/selectivity of this column allows for the separation of the Freon 114 … (Acute toxicity, inhalation, category 4)\nIrritating to skin. (P202)\nWash thoroughly after handling. (Skin corrosion/irritation, category 2)\nIrritating to eyes. Physical Description. Forane is a registered trade name for Elf Atochem General Information 170.9. It is a non-flammable gas with a sweetish, chloroform-like odor with the critical point occurring at 145.6 °C and 3.26 MPa. (Specific target organ toxicity, single exposure, category 1)\nToxic if absorbed through skin. Use a full-face respirator with multi-purpose combination (US) or type ABEK (EN14387) respirator cartridges in absence of proper environmental control. 1,2-Dichlorotetrafluoroethane, or R-114, also known as cryofluorane ( INN ), is a chlorofluorocarbon (CFC) with the molecular formula ClFCCFCl. ALR-CFC-010S-2X. https://environmentalchemistry.com/yogi/chemicals/cn/Freon%A0113.html 17034 Class. Cat#. Many CFCs have been widely used as refrigerants, … R-114 is used in centrifugal chillers and is known for being used in the maritime industry or other applications where corrosion is more common. An R-114 Replacement Refrigerant for Centrifugal Chillers. When pressurized or cooled, it is a colorless liquid. Three patients aged 32, 24 and 23 years respectively, accidentally inhaled Freon 12 gas which had leaked from an ait conditioning system of a ship. Hazard Codes: For the best experience on our site, be sure to turn on Javascript in your browser. The material was extruded through a 1/8 inch by 3 inch slot and the resultant foam was 1 inch by 5 inches with a … US4110269A US05/764,181 US76418177A US4110269A US 4110269 A US4110269 A US 4110269A US 76418177 A US76418177 A US 76418177A US 4110269 A US4110269 A US 4110269A Authority US United States Prior art keywords foam weight melt freon ionomer resin Prior art date 1977-01-31 Legal status (The legal status is an assumption and is not a legal conclusion. Freon™ 124 (R-124) refrigerant is a hydrochlorofluorocarbon (HCFC) retrofit replacement for R-114 used in centrifugal chillers and high-ambient cooling applications, including overhead cranes. (P264)\nRespiratory Protection: If workplace exposure limit(s) of product or any component is exceeded (see TLV/PEL), or a risk assessment shows air-purifying respirators are appropriate, use of a NIOSH/MSHA approved air supplied respirator is advised. Because of a growing concern over stratospheric ozone depletion and its attendant dangers, a ban was imposed on the use of CFCs in aerosol-spray dispensers in the late 1970s by the United States, Canada, and the Scandinavian countries.In 1990, 93 nations agreed, as part of the Montreal Protocol (established 1987), to end production of ozone-depleting chemicals by the end of the 20th century. 1,2-Dichlorotetrafluoroethane, or R-114, also known as cryofluorane (INN), is a chlorofluorocarbon (CFC) with the molecular formula ClF2CCF2Cl. Never give anything by mouth to an unconscious person. Matrix. Refer to SDS for detailed product information. Wash clothing before reuse. Lewis structures for ammonia (left), water (center), and hydrofluoric acid (right). Thomas Midgley Jr, Thomas Midgley Jr. (1889 – 1944) American mechanical and chemical engineer. Engineering and/or administrative controls should be implemented to reduce exposure.\nProtective gloves must be worn to prevent skin contact. Eye contact: Immediately flush with plenty of water. Figure A illustrates the separation of a typical Freon mixture on the Alumina chloride PLOT column. Its primary use has been as a refrigerant. Draw the Lewis structure of C2Cl2F4 where each carbon contains one chlorine atom. CAS# 76-14-2. It is recognized that nontoxic and nonflammable refrigerants (Freon or chlorofluorocarbon (CFC)) were commercialized in the manufacture of chlorofluoro- derivatives of methane and ethane until the 1930s. Get medical attention if symptoms occur. Remove contaminated clothing. Colorless gas with a faint, ether-like odor at high concentrations.

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